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1.
Microbioerosion rates and microbioeroder community structure were studied in four Kenyan protected coral-reef lagoons using shell fragments of Tridacna giant clams to determine their response to the influence of terrestrial run-off. Fourteen different microbioeroder traces from seven cyanobacteria, three green algae and four fungi species were identified. The river discharge-impacted reef and ‘pristine’ reef showed similar composition but higher microbioeroder abundance and total cyanobacteria- and chlorophyte-bioeroded areas when compared with the other study reefs. Cyanobacteria dominated during the north-east monsoon (NEM) relative to the south-east monsoon (SEM) season, with algae and cyanobacteria being major microbioeroders in the river-impacted and pristine reefs. The rate of microbioerosion varied between 4.3 g CaCO3 m?2 y?1 (SEM) and 134.7 g CaCO3 m?2 y?1 (NEM), and was highest in the river-impacted reef (127.6 g CaCO3 m?2 y?1), which was almost double that in the pristine reef (69.5 g CaCO3 m?2 y?1) and the mangrove-fringed reef (56.2 g CaCO3 m?2 y?1). The microbioerosion rates measured in this study may not be high enough to cause concern with regard to the health and net carbonate production of Kenya’s coral reefs. Nevertheless, predicted increases in the frequency and severity of stresses related to global climate change (e.g. increased sea surface temperature, acidification), as well as interactions with local disturbances and their influence on bioerosion, may be increasingly important in the future.  相似文献   
2.
Recent studies of continental carbonates revealed that carbonates with similar fabrics can be formed either by biotic, biologically-induced, biologically-influenced or purely abiotic processes, or a combination of all. The aim of this research is to advance knowledge on the formation of carbonates precipitated (or diagenetically altered) in extreme, continental environments by studying biotic versus abiotic mechanisms of crystallization, and to contribute to the astrobiology debate around terrestrial analogues of Martian extreme environments. Both fossil (upper Pleistocene to Holocene) and active carbonate spring mounds from the Great Artesian Basin (South Australia) have been investigated. These carbonates consist of low-Mg to high-Mg calcite tufa. Four facies have been described: (i) carbonate mudstone/wackestone; (ii) phytohermal framestone/boundstone; (iii) micrite boundstone; and (iv) coarsely crystalline boundstone. The presence of filaments encrusted by micrite, rich in organic compounds, including ultraviolet-protectants, in phytohermal framestone/boundstone and micrite boundstone is clear evidence of the existence of microbial mats at the time of deposition. In contrast, peloidal micrite, despite commonly being considered a microbial precipitate, is not directly associated with filaments in the Great Artesian Basin mounds. It has probably formed from nanocrystal aggregation on colloid particulate. Thus, where biofilms have been documented, it is likely that bacteria catalyzed the development of fabrics. It is less certain that microbes induced calcium carbonate precipitation elsewhere. Trace elements, including rare earth element distribution from laminated facies, highlight strongly evaporative settings (for example, high Li contents). Carbon dioxide degassing and evaporation are two of the main drivers for an increase in fluid alkalinity, resulting in precipitation of carbonates. Hence, although the growth of certain fabrics is fostered by the presence of microbial mats, the formation of carbonate crystals might be independent from it and mainly driven by extrinsic factors. More generally, biological processes may be responsible for fabric and facies development in micritic boundstone whilst micrite nucleation and growth are driven by abiotic factors. Non-classical crystallization pathways (aggregation and fusion of nanoparticles from nucleation clusters) may be more common than previously thought in spring carbonate and this should be carefully considered to avoid misinterpretation of certain fabrics as by-products of life. It is proposed here that the term ‘organic-compound catalyzed mineralization’ should be used for crystal growth in the presence of organic compounds when dealing with astrobiological problems. This term would account for the possibility of multiple crystallization pathways (including non-classical crystallization) that occurred directly from an aqueous solution without the direct influence of microbial mats.  相似文献   
3.
2015年3月"海马"号遥控无人潜水器(ROV)在南海北部陆坡西部海域首次发现活动冷泉,并命名为"海马"冷泉,此后中国地质调查局广州海洋地质调查局先后组织了3个航次,对"海马"冷泉开展进一步勘查和研究。本次研究在综合分析4个航次调查数据的基础上,初步阐述"海马"冷泉的分布范围、地形地貌、生物群落、自生碳酸盐岩和流体活动等特征。总体而言,"海马"冷泉区地势平缓,气体渗漏现象非常发育,是以CH4为主要气体渗漏形成的活动冷泉区,且气体渗漏活动具有时空迁移性。气体碳同位素组成表明,海马冷泉区的CH4为混合成因气,且以微生物成因为主;"海马"冷泉区发育有多种类型的化能自养冷泉生物群落,冷泉区种类丰富,目前已报道了多个冷泉生物新种。这些发现为研究南海北部陆坡西部海域天然气水合物分解及其环境效应、冷泉生物生命起源与演化和南海与印度洋及太平洋物种迁移贯通等科学问题提供重要依据。  相似文献   
4.
双酶法制备低黏度辛烯基琥珀酸淀粉钠的工艺条件   总被引:4,自引:0,他引:4  
对双酶法制备用作微胶囊壁材的低黏度辛烯基琥珀酸淀粉钠的工艺路线与工艺条件进行了研究。正交实验结果表明 ,在酯化淀粉乳质量浓度 2 0 %、每 g淀粉α 淀粉酶的用量为 6SKBU的条件下 ,影响产品性能的各因素中 ,糖化酶的用量对产品的DE值和流度的影响最大 ,各因素的重要性依次是 :糖化酶的用量、糖化酶作用时间、α 淀粉酶保温作用时间。最佳工艺条件是 :α 淀粉酶保温作用时间 4min ,每 g淀粉糖化酶用量 0 .2GAU ,糖化酶作用时间 2 .5h ,此时产品的DE值为 30 ,流度为 80左右  相似文献   
5.
地下水资源可持续利用的一个急待解决的重要问题,是对地下水补给和更新能力的评价.利用环境同位素技术研究地下水的补给和可更新性是当前较为新颖的方法之一.在西北干旱、半干旱的隐伏岩溶地区,地下水埋藏条件复杂,常规的地质勘探方法所能提供的水文地质信息有限,环境同位素方法在研究地下水的补给及可更新能力方面发挥了优势,可对传统方法进行补充和验证.其结果表明,研究区隐伏岩溶水形成较早,且有大量现代水的混入,平均混入量为54%.说明区内隐伏岩溶水的补给和更新能力较好.环境同位素分析结果还显示,大岔河隐伏岩溶水为一相对独立、半开放的水文地质单元,其补给来源部分为流域内大气降水、地表水的补给,部分为东南部三道沟岩溶地下水的补给;根据环境同位素EPM模型计算,地下水的滞留时间为36 a.地下水储存量为1.314×108 m3; 储水系数为7.29×10-3.这一结果与传统勘探方法的计算结果基本吻合,说明环境同位素方法的实用性.  相似文献   
6.
Based on the δ13C and δ18O fluctuation of lacustrine carbonate, CaCO3 content and sporo-pollen data, a palaeoclimatic history of Bosten Lake during the Holocene has been outlined, several stages of climatic changes are divided, and the following result es are obtained: (1) Palaeoclimatic changes revealed by carbonate isotope around Bosten Lake are basically identical with that revealed by other geological records in Xinjiang. Environmental changes presented apparent Westlies Style model: during cold period, relative humidity increased, δ18O, δ13C and CaCO3 appeared low; but in warm periods, the dry regime aggravated. (2) The temperature reflected by δ18O exist evident features being increase in the late period during the Holocene. Together with the δ13C, pollen and CaCO3 analyses, several cold and warm phases which are of broad regional significance can be identified. The warm peaks occurred at about 11.0 ka B.P., 9.4 ka B.P., 7.5 ka B.P., 5.0 ka B.P., 3.0 ka B.P. and 2.0 ka B.P.; the cold peaks at 11.5 ka B.P., 10.5 ka B.P., 8.8 ka B.P., 5.5 ka B.P., 3.3 ka B.P., 2.2 ka B.P. and 1.5 ka B.P.. (3) Several climatic events with the nature of “abrupt climatic changes” are revealed in the periods of 11.0 ka B.P. −10.5 ka B.P., 9.4 ka B.P. −8.8 ka B.P., 5.5 ka B.P. −5.0 ka B.P. and 2.0 ka B.P. −1.5 ka B.P.. (4) The results show that carbonate isotopic record of lacustrine sediment in arid area is very sensitive to climatic changes, and may be play a very important role in understanding the features and mechanism of palaeoclimatic changes.  相似文献   
7.
A lacustrine carbonate sequence from Hawes Water, Lancashire, UK, has been studied using stable isotopic, lithological, pollen and mineral magnetic analysis. The data reveal four abrupt climatic oscillations in the Late‐glacial Interstadial leading up to the onset of the Loch Lomond Stadial. The data also point to climatic warming relatively early within the stadial, ca. 12 500 GRIP yr, prior to the onset of the Holocene. The oxygen isotope record is taken as a signature of climate forcing against which the response of the lake‐system can be monitored. By adopting this approach it is revealed that the response of the biological system to the rapid climatic oscillations is non‐linear and primarily a function of the antecedent conditions. A significant end‐Devensian isotopic excursion (A) is matched by only minor changes in the cold‐adapted floras and faunas. During the warmer interstadial, the response of the biological ecosystem (events B–D) is clearly influenced by thresholds: major changes in the catchment vegetation associated with relatively minor oscillations in the isotopic signature. The stratigraphical patterns reveal significant lag effects between the onset of climate deterioration and resulting changes in vegetation. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
8.
Granular carbonate deposits of Late Pleistocene to Early Holocene age, commonly referred to as ‘miliolite limestone’, occur in a linear belt, parallel to the southern coast of Saurashtra, India. In the present study area these carbonate deposits are found in select valleys between ridges and mounds of pyroclastic material present in the Deccan trap plateau. Two different depositional histories have been proposed for these sediments. The presence of marine bioclasts led to the postulation of a marine origin for these deposits. The second school of thought propounded redeposition of the coastal sediments by aeolian processes. Although a few features could not be explained by the proposed aeolian model, critical comparison of these two views favoured the aeolian origin. The mode of occurrence, lithological and structural attributes, and microscopic evidence presented here, also support a possible aeolian origin for these deposits. Experimental observation indicates that these carbonate aeolianites represent backflow deposits, which accumulated because of the flow separation caused by the presence of topographic highs. The conspicuous concave‐up geometry of the deposit conformed to the shape of the separation bulb. In view of the inferred depositional mechanism, the disposition of the deposits and the signature of the palaeoflow direction suggest that the carbonate particles were derived from the north‐western coast of Saurashtra by strong south‐easterly winds. Massive granular carbonates with outsized basement clasts appear to be the product of avalanching of granular material from the higher contours because of oversteepening of the primary deposit.  相似文献   
9.
In situ atomic force microscopy (AFM) has been used to compare the growth of pure calcite and the growth of calcite in the presence of sulfate ions from aqueous solutions at a constant value of supersaturation (S.I. = 0.89) with respect to calcite. The effect of sulfate ions on calcite growth rates is determined and a potential incorporation of sulfate ions is identified in the calcite during growth. Solutions supersaturated with respect to calcite with solution concentration ratio of one and a constant pH of 10.2, were prepared and sulfate was added as Na2SO4 aqueous solution. The solution composition was readjusted in order to keep the supersaturation and pH constant. PHREEQC was used to determine relevant solution concentrations. In situ AFM experiments of calcite growth were performed using a fluid cell and flowing solutions passed over a freshly cleaved calcite surface. Growth rates were determined from the closure of the rhombohedral etch pits induced by initial dissolution with pure water. The spreading rate of 2-dimensional nuclei was also measured. At low concentrations of sulfate (≤ 0.5 mM), no effect on the growth rate of the calcite was observed. At higher concentrations (2 to 3 mM) of sulfate, the growth rate increased, possibly because a higher concentration of calcium and carbonate was necessary to maintain the supersaturation constant. At much higher concentrations of additional sulfate (up to 60 mM) the growth rate of the calcite was substantially decreased, despite the fact that a further increase of calcium and carbonate was required. The morphology of 2-dimensional growth nuclei became increasingly elongated with increasing sulfate content. Measurements of step height showed that newly grown steps were approximately 1 Å higher when grown in high sulfate concentrations, compared to steps grown in sulfate-free solutions. At sulfate concentrations above 5 mM the growth mechanism changes from layer growth to surface roughening. These observations suggest that the new growth has incorporated sulfate into the calcite surface.  相似文献   
10.
Due to the high number of variables involved in mine profitability studies, it is often very difficult to establish connections among them in order to provide a blend of market saleable quality products. In this sense, analytical chemistry together with chemometry are essential and indispensable disciplines to tackle these studies. The aim of this work was to demonstrate the utility of these disciplines to carry out optimization studies of iron mines. For this purpose, one of the most important iron mines of the Iberian Peninsula was chosen, sited in the mountain range of Sierra Menera, near the location of Ojos Negros (Teruel, Spain). Geological, mineralogical and chemical composition of 148 samples was analyzed, corresponding to different depths of three drill holes (named TE1, TE2 and TE3). In particular, aspects concerning to chemical composition are very important, since the mean contents of certain elements, such as phosphorus, sodium and potassium, should be restricted to the established limits to prevent that companies can drive back the raw material if they do not fulfil the necessary requirements. On the other hand, the large number of analysed samples drove us to use a statistical processing of the data. Among other aspects, it provides a way to find possible connections among a high number of variables and classify samples into compositional groups sharing similar composition, in order to limit the mineralised area and to obtain enough information about the amount of those chemical elements associated to iron ores. Data obtained from all these analytical techniques were in good agreement and provide a methodology that can be of wide interest applied to different geological studies.  相似文献   
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